Viscosity at 50 °C — ISO 3104
This line sets the heating duty for the whole installation. Transfer pump sizing, heater capacity, separator throughput, burner or injector performance are all designed around a viscosity target at the point of use, and that viscosity is reached by temperature. A parcel delivered at 178 mm²/s and a parcel delivered at 120 mm²/s both pass as CST 180, but they need different tank and heater temperatures to arrive at the same viscosity at the nozzle. Ask for the actual measured value on the batch, not the grade limit, and set the heater controller from it.
Density at 15 °C and CCAI
Density is measured by hydrometer under ISO 3675 or, more precisely and more commonly today, by oscillating U-tube under ISO 12185. It does two jobs at once. Commercially it converts the volume you measured into the mass you paid for, using the volume correction factors of the ISO 91 petroleum measurement tables. Technically it feeds the Calculated Carbon Aromaticity Index, an estimate of ignition quality derived from density and viscosity:
CCAI = D − 140.7 × log[log(V + 0.85)] − 80.6, where D is density at 15 °C in kg/m³ and V is kinematic viscosity at 50 °C in mm²/s.
Work it through for a 180 cSt fuel at 985 kg/m³ and the answer is about 855, comfortably inside the RME 180 limit of 860. Work the same 180 cSt viscosity at the density ceiling of 991.0 kg/m³ and the answer is about 861, already outside it. In other words an RME 180 cannot sit at both its density ceiling and its viscosity ceiling at the same time, which is a useful arithmetic check when a certificate looks a little too convenient. A high CCAI signals a fuel that is slow to ignite. It matters most in medium-speed four-stroke engines, where ignition delay shows up as rough running and late burning, and least in a large boiler where residence time is generous.
Micro carbon residue — ISO 10370
The mass fraction of carbonaceous material left after the sample is pyrolysed under controlled conditions. It is the best single predictor of how heavily a fuel will foul: deposits on injector tips and burner nozzles, on exhaust valves, in the economiser and across the turbocharger. RME 180 caps it at 15.00 % m/m; RMG 180 allows 18.00 % m/m at the identical viscosity. On equipment with tight nozzle geometry and limited soot-blowing capacity, that three-point gap is the whole reason to specify RME rather than RMG and to accept the price difference that goes with it.
Ash, vanadium and sodium
Ash is the incombustible mineral fraction, measured by ISO 6245 — 0.070 % m/m maximum for RME 180 against 0.100 % m/m for RMG 180. Within the ash, vanadium and sodium are the two elements that drive high-temperature corrosion. Vanadium oxides and sodium sulphate form low-melting eutectics that deposit on and then dissolve the protective oxide layer on exhaust valve seats, turbine blades and superheater tubes. The damage is worst when the two appear together, so a fuel carrying modest vanadium but elevated sodium can be more aggressive than one carrying high vanadium and almost no sodium. Elevated sodium is also the classic fingerprint of seawater ingress: read it against the water result before accepting any other explanation.
Aluminium plus silicon — catalyst fines
The single most destructive contaminant in residual fuel. Aluminium silicate particles carried over from refinery catalytic cracking survive combustion, are harder than the metal they meet, and abrade cylinder liners, piston rings, fuel pump plungers and injector needles. RME 180 caps them at 50 mg/kg and RMG 180 at 60 mg/kg, but the delivered limit is not the working limit: engine builders commonly ask for no more than about 15 mg/kg at the engine inlet, which means the fuel has to be settled and centrifugally separated on board or on site, not merely strained through a filter. Cat fines are dense, they concentrate in tank bottoms and at the water interface, and stripping the last of a tank is precisely how a concentrated slug reaches an engine that has run happily on the same cargo for a week.
Water and total sediment
Water is limited to 0.50 % V/V under ISO 3733, and it is not a trivial line. Water carries sodium and cat fines with it, it is cargo mass you paid for and cannot burn, it steals heat in the pre-heater, and it is the direct cause of tank boil-over when a cold wet bottom is heated quickly. Total sediment aged, under ISO 10307-2, is limited to 0.10 % m/m and answers a different question: how much solid material will drop out of this fuel over time and after thermal ageing. That is the stability test, and it is the line most often absent from a thin certificate.
Flash point, hydrogen sulphide and acid number
Flash point minimum 60.0 °C by ISO 2719 Pensky-Martens closed cup is a safety floor written into international carriage rules, not a performance property. Hydrogen sulphide is capped at 2.00 mg/kg by IP 570, and note carefully that this is a liquid-phase limit which says nothing about what accumulates in a warm tank vapour space. Acid number, maximum 2.5 mg KOH/g by ASTM D664, was added to catch acidic contamination capable of attacking fuel pumps and bearings.
The used lubricating oil check
ISO 8217 requires residual fuel to be free of used lubricating oil and defines the test arithmetically. The fuel is deemed to contain used lubricating oil if calcium exceeds 30 mg/kg together with zinc above 15 mg/kg, or calcium exceeds 30 mg/kg together with phosphorus above 15 mg/kg. Ask for those three elements on the certificate. They are cheap to run, they are a direct indicator that waste streams have been blended into the cargo, and their absence from a certificate is itself a piece of information.